@SchulzGroup

Molecular inorganic chemistry @unirostock since 2006. We ❤ phosphorus, nitrogen, biradical(oid)s, molecular switches and unusual molecules.

schulz.chemie.uni-rostock.de/
Joined March 2021
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  • Following80
  • Followers1.7K
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chemistry-europe.onlinelibra… nicht work Conny

New Insights into Poly(Dichlorophosphazene) Synthesis via Me3Si─N═PCl3 Polymerization: An Experim...

Poly(dichlorophosphazene) synthesis via Me3Si─N═PCl3 polymerization was reinvestigated using quantum chemical calculations and experiments. A cationic initiator (Ph3PCl2) enables ambient-temperature...

chemistry-europe.onlinelibrary.wiley.com
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Chaopeng Hu
@ChaopengHuJul 4
Excited to share our new work published in @angew_chem！ We report the first isolable donor–acceptor-stabilized Si–E–Si trimetallylenes (E = Ge, Sn, Pb), exhibiting NIR absorption and enabling access to Ge(I) and Sn(I) radical anions. doi.org/10.1002/anie.6871080 Many thanks to Matthias (@DriessLab) and all co-authors. @AvHStiftung @TUBerlin #InorganicChemistry #MainGroupChemistry #Silylene
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Helten Group@HeltenGroupJMUJun 9
We are thrilled to share our latest publication in @ChemCommun together with @LabBraunschweig. Well done, and a big congratulations to @LeonieWuest, @Johannes_Chb and the whole team! doi.org/10.1039/D6CC02128J

Planarity-induced emission of neutral 1,2,3-diazaborines mediated by C–H borylation

Targeted, self-mediated ortho-C–H borylation of 1,2,3-diazaborines (DABs) provides a powerful tool for post-synthetic modification. The resulting C–H boryl

pubs.rsc.org
Johannes Chorbacher@Johannes_ChbJun 9
I am excited to share our final collaborative project with @LeonieWuest and the @LabBraunschweig, in which we report on stimuli-responsive tetracyclic 1,2,3-diazaborine-based PAHs. doi.org/10.1039/D6CC02128J
https://doi.org/10.1039/D6CC02128J

ALT https://doi.org/10.1039/D6CC02128J

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Excited to share our last work 🥳🥳🥳. A photoexcited triplet Ge that lasts hours and, while being there, breaks a few molecules, including benzene. We hope you like it. Our feeling: there's plenty of space for discovery on low-valent MG photochemistry nature.com/articles/s41557-0…

A photoexcited triplet state germylene with a half-life of hours at room temperature

Nature Chemistry - Triplet tetrylenes are typically too short-lived for detailed investigation. Now a triplet germylene with a 14-h half-life at 25 °C has been generated through...

nature.com
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Nice HN3 chemistry
Powers Lab@Powers_LabMay 7
Our latest @ChemicalScience paper reports the first crystal structure of hydrazoic acid bound to a transition metal. Cryogenic photolysis reveals the elusive triplet dirhodium imidogen intermediate enabling stereospecific NH aziridination of olefins. doi.org/10.1039/D6SC02258H
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Phys.org
@physorg_comApr 22
A 3-atom ring made entirely of bismuth can sustain aromatic ring currents—despite being a heavy-metal cluster—and its aromaticity is dominated by sigma, not the usual pi, electrons. @AdmissionsUoM @NatureChemistry doi.org/hbxsck phys.org/news/2026-04-chemis…
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Organoboron Cycloarenes: Boron-Carbon Annulated Macrocyclic π-Systems ( @angew_chem ): onlinelibrary.wiley.com/doi/….
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Peter Coburger@CoburgerPeterMar 23
Very happy to see this finally out in print: A modular approach to unique cyclobutadienyl analogues! Congratulations to everyone involved, especially @StefanFrei1659 chemistry-europe.onlinelibra…

Modular Design Enables Access to Onium‐Substituted Diphosphacyclobutadienyl Complexes

A modular synthetic approach affords a series of cationic cobalt and manganese carbonyl half-sandwich complexes bearing onium-substituted diphosphacyclobutadienyl ligands. In this strategy, the...

chemistry-europe.onlinelibrary.wiley.com
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Having fun next to the brew kettle
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Ewpc in Dresden in a brewery...
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This exceptionally bulky ligand features trityl groups and a benzylated backbone that together create steric shielding that allows the isolation of rare low-coordinate metal complexes. chemistryworld.com/news/benz…
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News about my favorite element...beautiful chemistry
Reece Lister-Roberts@ReeceL_RFeb 10
2.5 years since we first discovered this compound and it’s finally out in @NatureChemistry! Have a read to learn about some surprisingly stable {N4} radical anions and there not so stable (and explosive) dianionic counterparts! nature.com/articles/s41557-0…

Crystalline nitrogen chain radical anions

Nature Chemistry - The isolation of catenated nitrogen compounds is difficult, in part because these chains can readily lose nitrogen, creating a strong thermodynamic push towards decomposition....

nature.com
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Awesome chemistry Silicon cyclopentadienides featuring a nonplanar 6π aromatic Si5 ring | Science science.org/doi/10.1126/scie…

Silicon cyclopentadienides featuring a nonplanar 6π aromatic Si5 ring

Compared with the wide variety of reports on carbon π-electron compounds, the silicon counterparts remain scarce because of the intrinsic preference of silicon to form σ-bonded compounds. In partic...

science.org
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Single-Carbon Bridged Pentacene Dimers Enable Efficient Singlet Fission and Quintet State Stabilization | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac… 興味深かった，というか

Single-Carbon Bridged Pentacene Dimers Enable Efficient Singlet Fission and Quintet State Stabili...

Abstract. Singlet fission (SF) offers a promising avenue for quantum information science, as it generates spin-entangled triplet pairs with quintet charact

pubs.acs.org
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Schulz Group retweeted
Josh Abbenseth@AbbensethJoshJan 7
📣Our new paper is out in @JACS (our very first one)!🥳 We show how a redox-active ligand unlocks C–X bond scission at an ambiphilic T-shaped Bi(III) compound. A big collaborative effort with my brilliant colleagues from Berlin. 👉pubs.acs.org/doi/10.1021/jac…

Ambiphilic Reactivity and Switchable Methyl Transfer at a T‑Shaped Bi(NNN) Complex Enabled by a...

Abstract. We report the transition-metal-like reactivity of a geometrically constrained, ambiphilic bismuth­(III) trisamide. Planarization of the Bi­(III)

pubs.acs.org
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Dispersion-Controlled Excited-State Dynamics in Azobenzene Photoisomerization | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

Dispersion-Controlled Excited-State Dynamics in Azobenzene Photoisomerization

Abstract. Weak interactions, like London dispersion forces, are cumulative in nature and have been thought to be essential for only the structure and stabi

pubs.acs.org
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Practicing for the Christmas lecture ... watch this little iron tree experiment under: https://www.youtube.com/watch?v=eQzgT0klY8c&list=PLT3fQg6hRZ7OW4xExAaDzWtrIfJu6Gcgj&index=38 Have a wonderful pre-Christmas season!

ALT Practicing for the Christmas lecture ... watch this little iron tree experiment under: https://www.youtube.com/watch?v=eQzgT0klY8c&list=PLT3fQg6hRZ7OW4xExAaDzWtrIfJu6Gcgj&index=38 Have a wonderful pre-Christmas season!

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Practising for the Christmas lecture ... see video: youtube.com/watch?v=eQzgT0kl… Have a wonderful pre-Christmas season
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Leon I. can now be called Dr. Leon I. Well done!
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Luminescent Perhalofluoro Trityl Radicals | Journal of the American Chemical Society @FU_Berlin pubs.acs.org/doi/10.1021/jac…

Luminescent Perhalofluoro Trityl Radicals

Abstract. In this proof-of-concept study, we show that polyfluorinated trityl radicals with the, to this date, highest fluorination grade can be accessed i

pubs.acs.org
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