@SankashM

student at indian Institute of science, bangalore..

Joined May 2020
  • Tweets71
  • Following315
  • Followers80
Check out our new article on Catalytic Asymmetric Allylic Substitution with Alkynylogous Silyl Enol Ethers En Route to Chiral Allenes from SM lab, IISC Bangalore pubs.acs.org/accacs/article-…

Catalytic Asymmetric Allylic Substitution with Alkynylogous Silyl Enol Ethers En Route to Chiral...

AbstractDespite their potential as building blocks of allenes, alkynylogous enol silanes have rarely been employed in organic synthesis. Herein, we establi

pubs.acs.org
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Sankash Mitra retweeted
Santanu Mukherjee@LabMukherjeeOct 16
Alkynylogous enol silanes on allylation result in chiral allenes. Just out in @ACSCatalysis: doi.org/10.1021/acscatal.6c0… Congratulations @SankashM and @DebangshuG17683 @iiscbangalore. We thank @SyngeneIntlCSR and @serbonline for funding.
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Replying to @LabMukherjee @SankashM @iiscbangalore @brianstoltz70
Congratulations to @sankashM and @LabMukherjee for an outstanding viva-voce. Best wishes for all your future endeavours.
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Congratulations, Sankash @SankashM, for successfully defending your PhD thesis at @iiscbangalore! We thank Prof. Nitin Patil @ThePatilGroup for conducting the thesis viva in hybrid mode. We also thank Prof. Brian Stoltz @brianstoltz70 for reviewing the thesis.
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NOST@NOST_India5 Mar 2025
Kicking off the BASF Session at #NOSTOCC2025, Prof. Santanu Mukherjee from @iiscbangalore delivered a captivating talk on "Symmetry Breaking Routes to Natural and Unnatural Ladderanes." Unlocking new strategies for constructing these fascinating molecular architectures!
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Fresh out of @LabMukherjee in @J_A_C_S: Alkoxy-directed dienamine catalysis and its application to the enantioselective synthesis of benzo-[3]-ladderanol: pubs.acs.org/doi/10.1021/jac… Congratulations @RaySayanray @iiscbangalore! Thank you, @serbonline, for funding.

Alkoxy-Directed Dienamine Catalysis in [4 + 2]-Cycloaddition: Enantioselective Synthesis of...

Abstract. Despite tremendous progress of dienamine catalysis along with its application in enantioselective synthesis over nearly two decades, certain limi

pubs.acs.org
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JACS Au@JACS_Au27 Dec 2024
Extended silyl enol ethers have now been utilized as nucleophile under iridium catalysis for the first enantioselective (bis)vinylogous allenylic substitution and create a remote stereocenter @LabMukherjee @iiscbangalore Read the paper 👉 go.acs.org/c3D
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Our work on the first catalytic enantioselective bis(vinylogous) allenylic alkylation is now out in @JACS_Au: pubs.acs.org/doi/10.1021/jac… Congratulations Sankash @SankashM Thank you, Syngene International Ltd. @SyngeneIntlCSR, and @iiscbangalore for funding

Iridium-Catalyzed Enantioselective Vinylogous and Bisvinylogous Allenylic Substitution

Abstract. Compared to the widely explored enol silanes, the applicability of their extended variants especially as bisvinylogous nucleophiles in enantiosel

pubs.acs.org
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CV Lab@lab_cv22 Jul 2024
For those who missed it: today we were very happy about this article with case studies to get new ideas... Thank you @MinteerLab A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms - now published in Chemical Science pubs.rsc.org/en/content/arti…

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms

Monitoring reactive intermediates can provide vital information in the study of synthetic reaction mechanisms, enabling the design of new catalysts and met

pubs.rsc.org
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Congratulations to the @MacMillan_Lab for their latest, just out in @Nature: “Unlocking carbene reactivity by metallaphotoredox a-elimination.” Great work by Ben, Nathan, Dave and colleagues at Janssen: bit.ly/4ebrtsH
Illustrative journal graphic courtesy of Ben Boyle.

ALT Illustrative journal graphic courtesy of Ben Boyle.

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A recent work from @LabMukherjee by Sankash @SankashM on the first catalytic enantioselective bis(vinylogous) allenylic alkylation is now ChemRxived: chemrxiv.org/engage/chemrxiv… Thank you, Syngene International Ltd. @SyngeneIntlCSR, for funding this research.

Iridium-Catalyzed Enantioselective Vinylogous and Bisvinylogous Allenylic Substitution | ChemRxiv

Compared to the widely explored enol silanes, applicability of their extended variants especially as bisvinylogous nucleophile in enantioselective catalysis has been sparse. Herein, we describe the...

chemrxiv.org
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Jacobsen Lab@JacobsenLab7 Mar 2024
Didn’t know a Wittig reaction could be enantioselective? Check out the latest instalment of our work in chiral lithium isothiourea boronates! pubs.acs.org/doi/10.1021/jac…

Enantioselective Potassium-Catalyzed Wittig Olefinations

Abstract. We report asymmetric potassium–isothiourea–boronate-catalyzed Wittig olefinations of 4-substituted cyclohexanones with non-stabilized phosphorus

pubs.acs.org
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Science ministry proposes new Rashtriya Vigyan Puraskar as India’s highest science & tech honour theprint.in/?p=1766048
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Enantioselective #TotalSynthesis of (+)-Pedrolide by Marlene Fadel and Erick M. Carreira @CarreiraGroup at @ETH_DCHAB in @J_A_C_S pubs.acs.org/doi/10.1021/jac…
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Prof. Feynman
@ProfFeynman26 Jul 2022
If you want to master something, teach it.
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Prof. Feynman
@ProfFeynman6 Apr 2023
• Study hard. • What others think of you is none of your business. • It's OK not to have all the answers. • Experiment, Fail, Learn and Repeat. • Knowledge comes from experience. • Imagination is important. • Do what interests you the most. • Stay curious
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Our scientific higher authorities should encourage to Indian Research Scholars towards science & research rather than ignored their request👇 #Hike_in_fellowship_22 @PMOIndia @EduMinOfIndia @IndiaDST @ppbajpai @srivaric @DrJitendraSingh @dpradhanbjp @varungandhi80 @Xpress_edex
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Why Indian Research Scholars are demanding?👇@srivaric #Hike_in_fellowship_22 #Regular_Disbursement_of_fellowship #Stop_PhD_Scholars_Harassment #Just waiting for official memo yet @PMOIndia @DrJitendraSingh @FinMinIndia @dpradhanbjp @Xpress_edex @the_hindu @IndiaDST @ppbajpai
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Rahul Banerjee@banerjee_r10 Jan 2023
Special thanks to @serbonline @IndiaDST @AvHStiftung @iiserkol for funding and support.
Rahul Banerjee@banerjee_r10 Jan 2023
Covalent Organic Framework Thin-Film Photodetectors from Solution-Processable Porous Nanospheres by Saikat Bag, with Himadri, Sonu, Kaushik, Dominic, Roman, Yingying, Miroslav, Agnieszka, and Ankita Shelke. Saikat worked for two years with @HimadriSasmal, @kaushik_chem, and Sonu.
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Our recent work on Ir-AAA:
J Org Chem/Org Lett@JOC_OL7 Apr 2021
A new prochiral nucleophile, namely deconjugated butyrolactam, is employed for Ir-catalyzed asymmetric allylic alkylation and leads to α-allyl products with moderate to good dr and excellent er from @LabMukherjee @iiscbangalore in #OL: buff.ly/2PzZGMt
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