@3Doperator

undergrad @pushingarrows @RiceUniversity| Former intern @EngleLab šŸ“€šŸŽ¹ šŸŽļøšŸš“šŸ­

 Houston | Shanghai
Joined September 2019
  • Tweets44
  • Following344
  • Followers225
7Media
Excited to start the new year with this new method for photocatalytic hydro- and deuterochlorination in @NatureSynthesis! A tour de force led by @KangjieBian! nature.com/articles/s44160-0ā€¦

Anti-Markovnikov hydro- and deuterochlorination of unsaturated hydrocarbons using iron photocatal...

Nature Synthesis - Methods for the anti-Markovnikov-selective hydrochlorination of unsaturated Cā€“C bonds are limited by the need for stoichiometric reagents, highly oxidizing photocatalysts...

nature.com
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Now online: Article by @KangjieBian, D Nemoto, Y Chen @YenChu_TW, @SCK64778810, @3Doperator, A A. MartĆ­ & @pushingarrows Anti-Markovnikov hydro- and deuterochlorination of unsaturated hydrocarbons using iron photocatalysis nature.com/articles/s44160-0ā€¦ ($)

Anti-Markovnikov hydro- and deuterochlorination of unsaturated hydrocarbons using iron photocatal...

Nature Synthesis - Methods for the anti-Markovnikov-selective hydrochlorination of unsaturated Cā€“C bonds are limited by the need for stoichiometric reagents, highly oxidizing photocatalysts...

nature.com
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Xiaowei Chen retweeted
Song Lin Lab@SongLinLab25 Oct 2024
We are thrilled to welcome five stellar 1st year students to the Lin Lab! Congrats to Bofei, Nayan, Evan, Joe and Xiaowei! Hereā€™s to new friends and great science aheadšŸ¤©āš”ļø
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u-of-o-nmr-facility.blogspotā€¦ Great source
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Bri Barbu@bri_barbu16 Feb 2024
When it comes to the catalysts that chemists rely on to assemble organic molecules, some metals are just greener than others...right? In my latest C&EN feature, I attempt to explain why that question doesn't (yet) have a simple answer: cen.acs.org/synthesis/catalyā€¦

The elements of a green catalyst

Making homogeneous catalysis greener is about more than just swapping out precious metals for earth-abundant ones

cen.acs.org
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Last class of (probably) last class of Prof. Paul Engel at Rice. šŸŽ“ Grateful for the knowledge gained in his spectroscopy and phys ochem class and this photochemistry class! ā€“ at Houston, TX
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The take away from this class: energy (kcal) = 28600 / wavelength (nm)
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Delighted to share a creative approach to general iron photocatalyzed alkene difunctionalization developed by @KangjieBian, David Nemoto, @3Doperator, @SCK64778810, and James Hooson published as a HOT article in @ChemicalScience pubs.rsc.org/en/content/artiā€¦

Photocatalytic, modular difunctionalization of alkenes enabled by ligand-to-metal charge transfer...

Ligand-to-metal charge transfer (LMCT) is a mechanistic strategy that provides a powerful tool to access diverse open-shell species using earth abundant el

pubs.rsc.org
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Xiaowei Chen retweeted
Bri Barbu@bri_barbu14 Nov 2023
"Basically any fluorinated fragment that you can get the carboxylic acid of is now fair game for adding into a moleculeā€ in @pushingarrows and team's new Nature Chemistry paper cen.acs.org/synthesis/fluoriā€¦

A cheap, flexible fluoroalkylation

Scientists invent a versatile method for attaching fluorinated groups to alkenes using inexpensive feedstocks and Earth-abundant catalysts

cen.acs.org
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The paper! nature.com/articles/s41557-0ā€¦ As a note, "HAT" was accidentally replaced by "XAT" in many instances during production and this is getting fixed!
Julian West@pushingarrows14 Nov 2023
I never imagined we would get the chance to be highlighted in @cenmag By the fantastic @bri_barbu!! A great write up of some cool chemistry developed by @KangjieBian, @YenChu_TW, David Nemoto, @SCK64778810, and @3Doperator Out in @NatureChemistry! cen.acs.org/synthesis/fluoriā€¦

A cheap, flexible fluoroalkylation

Scientists invent a versatile method for attaching fluorinated groups to alkenes using inexpensive feedstocks and Earth-abundant catalysts

cen.acs.org
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I never imagined we would get the chance to be highlighted in @cenmag By the fantastic @bri_barbu!! A great write up of some cool chemistry developed by @KangjieBian, @YenChu_TW, David Nemoto, @SCK64778810, and @3Doperator Out in @NatureChemistry! cen.acs.org/synthesis/fluoriā€¦

A cheap, flexible fluoroalkylation

Scientists invent a versatile method for attaching fluorinated groups to alkenes using inexpensive feedstocks and Earth-abundant catalysts

cen.acs.org
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There's a poem column on @ChemistryViews šŸŽƒ featuring radioactive elements I cannot distinguish.
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BREAKING NEWS The Royal Swedish Academy of Sciences has decided to award the 2023 #NobelPrize in Chemistry to Moungi G. Bawendi, Louis E. Brus and Alexei I. Ekimov ā€œfor the discovery and synthesis of quantum dots.ā€
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Todayā€™s win: Did a very short column and got the product (E)-2-phenylethenesulfonyl fluoride crystallized on rotovap ā€“ at La Jolla, San Diego
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Congrats to @theBrianFunk, @MartinPauze, @YenChu_TW, @Austinjacious, and Gemma on publication of their ingenious VB12/thiol epoxide reduction system in @CellRepPhysSci!! So proud to have two awesome projects from our group @RiceChemistry published today! cell.com/cell-reports-physicā€¦

Vitamin B12 and hydrogen atom transfer cooperative catalysis as a hydride nucleophile mimic in...

Here, Funk etĀ al. develop a mild synthetic method for hydrogenative epoxide ring opening. The co-catalytic system uses Earth-abundant vitamin B12 and TRIP thiol to efficiently produce Markovnikov...

cell.com
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Congrats to @SCK64778810, @KangjieBian, @3Doperator, Ying, and @AngelMartiLab on publication of their creative work in @ChemCatalysis!! Direct conversion of carboxylic acids to azides using sustainable iron photocatalysis! @RiceUniversity cell.com/chem-catalysis/fullā€¦

Photochemical iron-catalyzed decarboxylative azidation via the merger of ligand-to-metal charge...

Decarboxylative azidation is a powerful approach to prepare Cā€“N bonds in bioactive molecules. However, previous methods require strong oxidants, precious metals, complex reagents, and/or carboxylic...

cell.com
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I just learned about ladderene today in Chem 656. A Metal-Free Cyclobutadiene Reagent for Intermolecular [4 + 2] Cycloadditions pubs-acs-org.ezproxy.rice.edā€¦
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I bought the total synthesis series last year. Finally started reading for CHEM 656 tomorrow.šŸ¤“šŸ˜ŽšŸ˜†
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HAT lessons help hydrogen hop, skip, and jump

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Chemoselective Decarboxylative Protonation Enabled by Cooperative Earth-Abundant Element Catalysis (West) @pushingarrows @YenChu_TW @RiceChemistry @RiceUniversity onlinelibrary.wiley.com/doi/ā€¦
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