Associate Professor of Chemistry @UCRiverside. Silicon Chemistry, Atomically Precise Materials, Molecular Electronics.

Riverside, CA
Joined December 2010
Very honored! Thanks to @dreyfusfndn, @ChemistryUCR Dept, and my letter writers for their support. Above all, thanks to the members of my research group at UCR, whose creativity and determination have allowed us to advance this exciting new area of molecular silicon electronics!
Replying to @dreyfusfndn
Congratulations to Dr. Timothy Su (@TimothyASu), @UCRiverside, for being named a 2026 Camille Dreyfus Teacher-Scholar! @ChemistryUCR #DreyfusAwards
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Our (@chemheechan, @gilliardgroup) manuscript with @cromeronieto and team on Ge- and B-doped hexacene derivatives is now online in @ChemicalScience! We unveil Ge-B exchange as a method to obtain extended B-acenes. #maingroup pubs.rsc.org/en/content/arti…
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Aluminum: lightest p-block metal with very low electronegativity. Converting Al(III) to Al(I) in stoichiometric reactions is rare. But now, we've made Al redox catalysis a reality! Check it out @nature nature.com/articles/s41586-0…
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Excited to start the work with a chemist @TimothyASu on silicon color center with atomic synthetic precision! Thanks RCSA and other sponsors!
RCSA, The Brinson Foundation, @SimonsFdn and Kevin Wells have awarded funding to 7 cross-disciplinary teams of researchers in the inaugural year of  #Scialog: Quantum Matter and Information. wp.me/pgj04D-ayi
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Since my days as a graduate student, I have been interested in using carboranes as substituents on heteroatoms to tune electronics, similar to classical alkyl and aryl groups. Over the years, our group and others have demonstrated that C-bound carboranes are actually strongly electron withdrawing, comparable to classical perfluoroarenes. In our latest preprint (tinyurl.com/2mndp5j2), Vicki Rubio shows that this concept extends to the heavy pnictogens, revealing that carborane substitution allows for the construction of highly Lewis acidic Sb(V) centers. A special shout out goes to all coauthors and especially Osvaldo Gutierrez and his team for their contributions to the theoretical and computational aspects of this work.
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Our work on an atomically precise PbSe nanocrystal has been published @J_A_C_S ! Congratulations to @fuyan_ma for achieving atomic precision in the PbSe nanocrystal and unveiling its structure with unprecedented resolution! pubs.acs.org/doi/10.1021/jac…
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Replying to @TimothyASu @J_A_C_S
Congrats to Lan, Matt, Grace, Ashley, and Lamia! Want to highlight here that Grace, an undergrad @UCRiverside, did the heavy lifting on revisions while Lan was on internship. Grace is applying for grad school this year and any program would be lucky to have her!
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Can redox active, Lewis acidic magnesium Pac-man complexes form stable "adducts" with alkanes? Jeremy, Matt, Joe and co’s latest pre-print @ChemRxiv says ”Hell Yeah”! Alkane C-H activation by a main group metal incoming? tinyurl.com/3f4c22sz #ozchem @ChemistryMonash @AFOSR
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How to obtain X-ray structural data of inherently amorphous compounds? Check-out the latest work by Yaofeng published in @NatureComms in the framework of @for2824 @dfg_public: rdcu.be/eCkXR
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Controlling Electrical Flow in Silicon through Quantum Interference azoquantum.com/News.aspx?new… via @AZoQuantum #UCRscience #silicon #technology #electronics #quantum #chemistry #ucr #ucriverside
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In our latest preprint, we introduce rhodamines as new scaffolds for molecular electronics. We harness rhodamine's lactone-zwitterion bistability to access on/off conductance ratios that are among the highest reported for chemically-induced switches. tinyurl.com/7r4wbpeb
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This project has been over 4 years in the making and is spearheaded by a multi-talented grad student, Lan Pham. Funding support is from @acsprf and @NSF.
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Our manuscript on unlocking the ambiphilicity of boryl anions is now published in @J_A_C_S (pubs.acs.org/doi/full/10.102…)! Chonghe, Junyi, Xibao, and coworkers report the synthesis and reactivity of the first anionic diazoborane! #maingroup @ccclabmit @gilliardgroup
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