The Wall

Risitas - Las Paelleras (Original video with English Subtitles)

EDIT - Just in case: I did both the translating and editing on this...

In Crystallo O2 Cleavage at a Preorganized Triiron Cluster | ChemRxiv

In Nature, the four-electron reduction of O2 is catalyzed at preorganized multimetallic active sites. These complex active sites often feature low-coordinate, redox-active metal centers precisely...

O2 Activation and Enzymatic C-H Bond Activation Mediated by a Dimanganese Cofactor | ChemRxiv

Dioxygen (O2) is a potent oxidant used by aerobic organisms for energy transduction and critical biosynthetic processes. Numerous metallocofactors, which most commonly feature iron or copper ions,...

A Widespread, Diiron-dependent Diterpenoid Hydroxylase | ChemRxiv

This communication describes the discovery of a family of monooxygenases that selectively hydroxylate abundant abietane diterpenoids. Previous studies on abietic acid metabolism had implicated an...

Bioinformatic Discovery of a Cambialistic Monooxygenase | ChemRxiv

Dinuclear monooxygenases mediate challenging C-H bond oxidation reactions throughout Nature. Many of these enzymes are presumed to exclusively utilize diiron cofactors. Herein, we report the bioinf...

Four – Electron Oxidative Addition of an N=N Double Bond at a Chromium Metallocyclopropene |...

This report describes the synthesis of a pseudo-tetrahedral chromium alkyne complex supported by a bidentate phosphinimide ligand and its reactivity with azobenzene. Characterization of the former by...

Multielectron Bond Cleavage Processes Enabled by Redox-Responsive Phosphinimide Ligands | ChemRxiv

The activation of small molecules via multi-electron redox processes offers promise in mediating difficult transformations related to energy conversion processes. While molecular systems that engage...