@MindiolaGroup
 University of Pennsylvania
mindiolagroup.chem.upenn.edu
Joined October 2015
  • Tweets185
  • Following297
  • Followers1.9K
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Beautiful chemistry and route to phosphinidene and phosphide from Jacob Mohar in our group! Check it out in JACS! pubs.acs.org/doi/10.1021/jac…

Titanium Phosphinidene and Phosphide Moieties from Oxidative Phosphorylation and Desilylation

Abstract. A unique entry into mononuclear titanium complexes bearing phosphinidene and phosphide ligand moieties is reported. Reaction of [K­(crypt)]­[(PN)

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Wonder work from @MrinalBhunia exploring the structure and reactivity of molecular phosphide complexes of zirconium! pubs.acs.org/doi/10.1021/jac…

Molecular Phosphide Complexes of Zirconium

Abstract. Molecular ZrIV phosphides are extremely rare, with no examples containing a one-coordinated and terminal triple-bonded phosphorus atom. We report

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More great work from @JohnRuss19 with titanium neopentylidene complexes! pubs.acs.org/doi/10.1021/acs…

Isonitrile Insertion into Titanium Neopentylidene Alkyl Complexes Yields a Bifurcated Pathway to...

Abstract. Three organometallic ligand scaffolds resulting from the insertion of 1-adamantyl isonitrile (CNAd; Ad = C10H15) into titanium neopen

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Check out @EthanZars latest paper in Organometallics! Isolation of a Fe(III) carbene radical complex! pubs.acs.org/doi/10.1021/acs…

Divergent Reactivity of Azides and Diazoalkanes Toward Ferrous Complexes and Isolation of a FeIII...

Abstract. Treatment of [(tBupyrr2pyr)­Fe­(OEt2)] (1-OEt2) (tBupyrr2pyr2– = 3,5-tBu2-bis­(pyrrolyl)­pyridine) with trimethylsilyl azide (N3SiMe3) and subseq

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Now all the elements can get in on the fun! Check out our latest work in @ChemicalScience! Pnictogen-Based Vanadacyclobutadiene Complexes. pubs.rsc.org/en/content/arti… Thanks to Afshan, @JohnRuss19, @baikkaist 💻, and @UPennXtal 🔮for their contribitions!

Pnictogen-based vanadacyclobutadiene complexes†

The reactivity of the V≡CtBu multiple bonds in the complex (dBDI)V≡CtBu(OEt2) (C) (dBDI2− = ArNC(CH3)CHC(CH2)NAr, Ar = 2,6-iPr2C6H3) with unsaturated subst

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Check out @EthanZars latest paper in ChemComm! Csp2–H/F bond activation and borylation with low valent iron - now published in Chemical Communications pubs.rsc.org/en/content/arti…

Csp2–H/F bond activation and borylation with iron†

Reduction of [K2{(tBupyrr2pyr)Fe}2(μ-N2)] (1) with two equiv. of KC8 in the presence of crown-ether 18-C-6 yields the N2 adduct [{K(18-C-6)}2(tBupyrr2pyr)F

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Mindiola Group retweeted
EZmoney@EthanZars12 Sep 2024
Pleased to share some of my graduate work published this week. Thanks to @mattmena_ for helping finish this project! – at Ann Arbor, MI
Mindiola Group@MindiolaGroup12 Sep 2024
Congrats to our Iron Man (@EthanZars) on another published mansucript! Check it our here! A Ferrous Adduct of a Phosphanylidene-σ4-phosphorane | Organometallics pubs.acs.org/doi/full/10.102…

Flash Communication: A Ferrous Adduct of a Phosphanylidene‑σ4‑phosphorane

Abstract. The sterically encumbered phosphanylidene-σ4-phosphorane Mes*PPMe3 (Mes* = 2,4,6-tBu3C6H2) smoothly displaces Et2O in [(tBupyrr2py)­Fe­(OEt2)] (1

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Mindiola Group retweeted
Organometallics@Orgmet_ACS12 Sep 2024
Organometallic chemistry in a Flash! Reviving short communications, check out the first Flash Communication from @MindiolaGroup on iron phosha-Staudinger adducts. go.acs.org/aPb

Flash Communication: A Ferrous Adduct of a Phosphanylidene‑σ4‑phosphorane

Abstract. The sterically encumbered phosphanylidene-σ4-phosphorane Mes*PPMe3 (Mes* = 2,4,6-tBu3C6H2) smoothly displaces Et2O in [(tBupyrr2py)­Fe­(OEt2)] (1

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Hey all! Check out @mattmena_ first (first author!!!) publication in the group! Molecular Bis(chalcogenido) Titanates of Te, Se, and S | Inorganic Chemistry pubs.acs.org/doi/full/10.102…

Molecular Bis(chalcogenido) Titanates of Te, Se, and S

Abstract. A series of titanate cisoid bis­(chalcogenidos) (Ch = Te, Se, and S) complexes supported by the β-diketiminate ligand BDI– = [ArNC­(CH3)]2CH (Ar

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@MrinalBhunia @UPennXtal
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Congrats to our Iron Man (@EthanZars) on another published mansucript! Check it our here! A Ferrous Adduct of a Phosphanylidene-σ4-phosphorane | Organometallics pubs.acs.org/doi/full/10.102…

Flash Communication: A Ferrous Adduct of a Phosphanylidene‑σ4‑phosphorane

Abstract. The sterically encumbered phosphanylidene-σ4-phosphorane Mes*PPMe3 (Mes* = 2,4,6-tBu3C6H2) smoothly displaces Et2O in [(tBupyrr2py)­Fe­(OEt2)] (1

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What a pleasure to give a seminar at the Department of Chemistry Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) and meeting great scientists and old friends. Thank you @Karsten Meyer and the team for hosting me. ⁦@MindiolaGroup⁩
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Divalent Titanium via Reductive N-C Coupling of a TiIV Nitrido with pi-Acids (Daniel J. Mindiola and co-workers) @MindiolaGroup @MrinalBhunia #openaccess onlinelibrary.wiley.com/doi/…

Divalent Titanium via Reductive N−C Coupling of a TiIV Nitrido with π‐Acids

A titanium nitride undergoes N−C bond coupling with carbon monoxide and isocyanides to form TiII cumulene complexes [(PN)2Ti(NCE)]− (E=O, NAd, NtBu). Oxidation of these affords the TiIII cumulene...

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Come check out our lastest work now in @J_A_C_S Congrats to Shuruthi and co-workers for there amazing job on this story!
J. Am. Chem. Soc.@J_A_C_S4 Jun 2024
A Vanadium Methylidene | Journal of the American Chemical Society @MindiolaGroup @Penn @PennChemistry #Vanadium #Methylidene pubs.acs.org/doi/10.1021/jac…

A Vanadium Methylidene

Abstract. Examples of stable 3d transition metal methylidene complexes are extremely rare. Here we report an isolable and stable vanadium methylidene compl

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A collaborative effort of great researchers @MindiolaGroup @MrinalBhunia @group_comic Dominik Fehn Laurent Grant Shuruthi Senthil Michael R. Gau Andrew Ozarowski J. Krzystek Joshua Telser Balazs Pinter Karsten Meyer
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Ynamide and Azaalleneyl. Acid-Base Promoted Chelotropic and Spin-State Rearrangements in a Versatile Heterocumulene [(Ad)NCC(tBu)]- (Daniel J. Mindiola and co-workers) @mindiolagroup @baikkaist #openaccess onlinelibrary.wiley.com/doi/…

Ynamide and Azaalleneyl. Acid‐Base Promoted Chelotropic and Spin‐State Rearrangements in a Versat...

In this communication, we highlight the chelotropic rearrangement of a relatively rare heterocumulene, [(Ad)NCC(tBu)]− on a [VIII] core from κ1-N-ynamide to a κ2-C,N-azaalleneyl and vice versa, with...

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Check out our latest work in @angew_chem! @MrinalBhunia shows that a Ti(IV) nitride undergoes N-C bond coupling with CO and CNR to form a series of Ti(II) cumulenes. onlinelibrary.wiley.com/doi/…

Divalent Titanium via Reductive N−C Coupling of a TiIV Nitrido with π‐Acids

A titanium nitride undergoes N−C bond coupling with carbon monoxide and isocyanides to form TiII cumulene complexes [(PN)2Ti(NCE)]− (E=O, NAd, NtBu). Oxidation of these affords the TiIII cumulene...

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In our latest report in @angew_chem, @JohnRuss19 and co-workers discuss the chelotropic and spin-state rearrangement on the heterocumulene [(Ad)NCC(tBu)]- on the V[III] metal center. onlinelibrary.wiley.com/doi/…

Ynamide and Azaalleneyl. Acid‐Base Promoted Chelotropic and Spin‐State Rearrangements in a Versat...

In this communication, we highlight the chelotropic rearrangement of a relatively rare heterocumulene, [(Ad)NCC(tBu)]− on a [VIII] core from κ1-N-ynamide to a κ2-C,N-azaalleneyl and vice versa, with...

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This work gave us some great insight into the ring (spring) opening of these cumulated metallacyclobutadienes!
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Thanks to @baikkaist team for comuptational help 🖥️! And to Josh and Andrew and the @NationalMagLab for the magnetic/electronic insights for this unique system 🧲!
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