Marburg, Germany
Joined July 2015
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C-H oxygenation via nitrene chemistry? Yes, quite surprising! Checkout our newest work in Angewandte Chemie.
onlinelibrary.wiley.com/doi/…
Interesting work from Murakami lab in @J_A_C_S on photoinduced carboxylation of C-H bonds with carbon dioxide. Works with simple alkanes such as cyclohexane. pubs.acs.org/doi/10.1021/jac…
Nice Glühwein at the Marburg Chirstmas Market after discussing research with Keisuke Umakoshi and Masanari Kimura (both Nagasaki University). Thank you for having visited us in Marburg!
Chiral rhodium photocatalysts: Our newest "family member" applied to asymmetric photoredox cyanoalkylations. onlinelibrary.wiley.com/doi/…. #Chiral, #asymmetric, #catalysis.
Our newest work on the design of chiral-at-metal catalysts in collaboration with the Houk group at UCLA: pubs.acs.org/doi/full/10.102…. Intramolecular C-H amidation at catalyst loadings down to 0.005 mol%! But only with the non-C2 symmetric diastereomer of the catalyst.
Our newest catalytic asymmetric photochemistry: pubs.acs.org/doi/abs/10.1021…. Allows to install adjacent all-carbon-quaternary stereocenters!
New Account article on our research on chiral-at-metal chiral Lewis acid catalysis: pubs.acs.org/doi/full/10.102…
Enantioselective, ultra low loading H-bond catalysis: J. Am. Chem. Soc. 2016, DOI: 10.1021/jacs.6b02769.
New rhodium catalyst from our lab: Dalton Transactions, 2016, DOI: 10.1039/C6DT01063F #catalysis
Checkout our recent work on asymmetric photoredox catalysis: onlinelibrary.wiley.com/doi/…
Chiral-at-metal iridium complex for efficient enantioselective transfer hydrogenation of ketones: DOI: 10.1039/C6CC00972G
Green asymmetric catalysis: onlinelibrary.wiley.com/doi/…
Note the use of a chiral Rh complex for visible-light-activated photoredox chemistry!
Checkout our latest publication on asymmetric photoredox catalysis with a chiral iridium complex: pubs.acs.org/doi/pdf/10.1021…