Official Twitter account for the Long Group in the @UCB_Chemistry Department @UCBerkeley and @BerkeleyLab

Berkeley, CA
Joined October 2018
New in @ScienceMagazine: We harness the remarkably low-entropy conversion of a Zn-hydride to Zn-formate species in an MFU-4l-type MOF to perform CO2 capture under high-temperature (H-O-T-T-O-G-O), industrially useful conditions. dx.doi.org/10.1126/science.a… cen.acs.org/materials/metal-…
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Congrats to Jeff on his election to the National Academy of Sciences! chemistry.berkeley.edu/news/…
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We show that metal-metal bonding in a trinuclear mixed-valence gadolinium cluster gives rise to S = 11 ground state. Thanks to @NAWS_CL, @nfchilton, and @rdavbritt. pubs.acs.org/doi/10.1021/jac…
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We stan MOF-74, which, incidentally, looks great on a sweater.
Round 4 of #MOFMadness (a collab w/ @KCarsch) is ready for your votes below! It’s down to the “Functional Four” — decide who will make it to the final round tomorrow in the grand finale of MOF Madness! Vote, vote, vote!
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Out now in @ScienceMagazine: we show that metal-metal bonding in mixed-valence dilanthanide complexes gives rise to enormous coercive magnetic fields at high temperatures. Thanks to @NAWS_CL, @nfchilton, @rdavbritt, @profanalytis, and @NationalMagLab. bit.ly/3I4mT
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Slow magnetic relaxation in a low-valent, group 5 isocyanide triad provides experimental evidence for the quadratic relationship between relaxation rate and spin-orbit coupling in single-molecule magnets. @UCB_Chemistry @maxplanckpress bit.ly/3DHxniK
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Geometric spin frustration is at play in a new manganese bromide nanosheet out in @InorgChem. bit.ly/3oRttiB
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Now in @J_A_C_S: We show that strong H2 binding at unsaturated Cu+ centers in Cu(I)-MFU-4l proceeds via a non-concerted pathway that involves a structurally characterized physisorbed precursor. @UCB_Chemistry @BerkeleyLab @HyMARC_Labs @BRBChemistry bit.ly/3jyxENw
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In our latest work in @J_A_C_S with @ReimerLab, we examine unusual CO2 uptake in the MOF dmen–Mg2(dobpdc) using non-traditional adsorption measurements, solid-state NMR, and DFT. bit.ly/3BRAdAw
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