
Official Twitter account for the Long Group in the @UCB_Chemistry Department @UCBerkeley and @BerkeleyLab
Berkeley, CA
Joined October 2018
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New in @ScienceMagazine: We harness the remarkably low-entropy conversion of a Zn-hydride to Zn-formate species in an MFU-4l-type MOF to perform CO2 capture under high-temperature (H-O-T-T-O-G-O), industrially useful conditions.
dx.doi.org/10.1126/science.a…
cen.acs.org/materials/metal-…
Congrats to Jeff on his election to the National Academy of Sciences!
chemistry.berkeley.edu/news/…
We show that metal-metal bonding in a trinuclear mixed-valence gadolinium cluster gives rise to S = 11 ground state. Thanks to @NAWS_CL, @nfchilton, and @rdavbritt. pubs.acs.org/doi/10.1021/jac…
We stan MOF-74, which, incidentally, looks great on a sweater.
Round 4 of #MOFMadness (a collab w/ @KCarsch) is ready for your votes below!
It’s down to the “Functional Four” — decide who will make it to the final round tomorrow in the grand finale of MOF Madness! Vote, vote, vote!
Three Ways Berkeley Lab is Accelerating Carbon Management Solutions to F... youtu.be/WXIYVvaDwqI via @YouTube
Out now in @ScienceMagazine: we show that metal-metal bonding in mixed-valence dilanthanide complexes gives rise to enormous coercive magnetic fields at high temperatures. Thanks to @NAWS_CL, @nfchilton, @rdavbritt, @profanalytis, and @NationalMagLab. bit.ly/3I4mT
Slow magnetic relaxation in a low-valent, group 5 isocyanide triad provides experimental evidence for the quadratic relationship between relaxation rate and spin-orbit coupling in single-molecule magnets. @UCB_Chemistry @maxplanckpress bit.ly/3DHxniK
Geometric spin frustration is at play in a new manganese bromide nanosheet out in @InorgChem. bit.ly/3oRttiB
Now in @J_A_C_S: We show that strong H2 binding at unsaturated Cu+ centers in Cu(I)-MFU-4l proceeds via a non-concerted pathway that involves a structurally characterized physisorbed precursor. @UCB_Chemistry @BerkeleyLab @HyMARC_Labs @BRBChemistry bit.ly/3jyxENw
In our latest work in @J_A_C_S with @ReimerLab, we examine unusual CO2 uptake in the MOF dmen–Mg2(dobpdc) using non-traditional adsorption measurements, solid-state NMR, and DFT. bit.ly/3BRAdAw






