@Jsperling91
 Golden, CO
Joined March 2018
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114Media
pubs.acs.org/doi/10.1021/jac…

Pressure-Induced Stabilization of Terbium(IV) in CsTb(CrO4)2 Characterized by X-ray Absorption...

Abstract. Single crystals of CsTb(CrO4)2 and CsDy(CrO4)2, where the lanthanide metals are in the trivalent state under ambient conditions, have been invest

pubs.acs.org
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Tyler did a fantastic job on this one. A deep dive into the chemistry and physics of transplutonium elements #fblockrocks journals.aps.org/rmp/abstrac…

Pressure effects on metals, alloys, and compounds of transplutonium elements

Materials containing transplutonium elements (the actinides Am--Cm that come after Pu in the periodic table) are important for nuclear power, nuclear waste management, and long-term storage. They...

journals.aps.org
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Sm2+ is reactive as hell. Pressure just makes it worse pubs.acs.org/doi/10.1021/acs…

Pressure-Induced Reduction of Dicyanamide by Samarium(II) in a Coordination Polymer

Abstract. A samarium­(II) coordination polymer, [Sm­(2.2.2-cryptand)­(dca)]­I (dca− = dicyanamide), has been prepared from the reaction of SmI2 with tetrab

pubs.acs.org
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nature.com/articles/s41467-0… I remeber seeing the americium crystals from like 20 ft away. Great job Nick! #fblockrocks

Non–linear bonding trends in maleonitrile-1,2–dithiolate complexes of the transuranium actinides

Nature Communications - Although the trivalent actinides are similar to the lanthanide series in terms of chemistry and bonding, their structures and properties can diverge significantly. Here, the...

nature.com
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Reactions of Np(VI) and Pu(VI) with Phenanthroline Result in Bending the [NpVIO2]2+ Unit and a Reduced Pu(V) Species | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

Reactions of Np(VI) and Pu(VI) with Phenanthroline Result in Bending the [NpVIO2]2+ Unit and a...

Abstract. Despite decades of actinyl chemistry, genuinely bent actinyl structures remain rare beyond uranium. We report the first crystallographic characte

pubs.acs.org
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Transuranium organometallic chemistry nature.com/articles/s41570-0… 🧪
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Neptunium (Np3+) has a beautiful alexandrite effect. Left is one lab, center is natural sunlight, and right is a lab under fluorescent lighting. 5f-5f transitions are magical. This is the same solution. Some great pics taken by @jp_brannon #fblockrocks #actinides
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249Bk (t1/2 ~330 days) is a beta blasting bully, but sometimes things work out #fblockrocks #bkallday pubs.acs.org/doi/10.1021/acs…

Effects of the Inverse Trans-Influence in a Berkelium(III) Phosphine Oxide Complex

Abstract. An example of a 249Bk3+ phosphine oxide complex has been prepared to examine and quantify the effects of the inverse trans-influence (ITI) on a l

pubs.acs.org
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Unveiling the covalency of versatile Pu(iii)-N bonds in a unique plutonium(iii) complex - now published in Chemical Science pubs.rsc.org/en/content/arti…

Unveiling the covalency of versatile Pu(iii)-N bonds in a unique plutonium(iii) complex†

A trivalent plutonium–pyrazinyl–tetrazolate complex Na2[Pu(Hdtp)(dtp)2(H2O)4]·9H2O (Pu_dtp, H2dtp = 2,3-di-1H-tetrazol-5-ylpyrazine) was synthesized throug

pubs.rsc.org
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Plutonium chemistry is wack, this compound is is another reason why plutonium is wack #fblockrocks pubs.rsc.org/en/content/arti…

Unveiling the covalency of versatile Pu(iii)-N bonds in a unique plutonium(iii) complex†

A trivalent plutonium–pyrazinyl–tetrazolate complex Na2[Pu(Hdtp)(dtp)2(H2O)4]·9H2O (Pu_dtp, H2dtp = 2,3-di-1H-tetrazol-5-ylpyrazine) was synthesized throug

pubs.rsc.org
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This is a neat set of compounds #fblockrocks #inorgchem pubs.acs.org/doi/10.1021/acs…

Elucidation of an Unusually Long Pu–N Bond in a Plutonium(III)-Tetrazolate Complex

Abstract. Four trivalent, f-element tetrazolate hydrate complexes [M­(H2O)9]­(Hdtb)3·nH2O (Nd1, n = 7 and Pu1, n = 9; dtb2– = 1,3-di­(tetrazolate-5-yl)­ben

pubs.acs.org
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Xenon Trioxide Coordination Complexes of Crown Ethers: (CH2CH2O)4XeO3 and Xe(VI) Hydrates, [(CH2CH2O)6(H2O)XeO3].H2O and [(CH2CH2O)6(H2O)XeO3]2.2H2O.HF (Gary J. Schrobilgen and co-workers) #openaccess #AngewandteVIP 🔓 onlinelibrary.wiley.com/doi/…

Xenon Trioxide Coordination Complexes of Crown Ethers: (CH2CH2O)4XeO3 and Xe(VI) Hydrates, [(CH2C...

Quenching xenon's thirst by its coordination to water in the 18-crown-6 complexes, [(CH2CH2O)6(H2O)XeO3] ⋅ H2O and [(CH2CH2O)6(H2O)XeO3]2⋅ 2H2O ⋅ HF, provides the first examples of Xe- - -O bonded...

onlinelibrary.wiley.com
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Excited to share the final version of Pr5+, now out in Nature Chemistry! Many thanks to co-authors, this was a huge lift from all fronts nature.com/articles/s41557-0… – at Wisconsin, USA
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This guy is finally out!! Glad to collaborate with @harder_research and @Sandeepthakur_K, and help them describe the first s-Block-Lanthanide bond! Awesome chemistry that you can now check out here in @J_A_C_S @ALGC_VUB 🚀🚀 pubs.acs.org/doi/10.1021/jac…

s‑Block Metal-Lanthanide Bonding: Direct Comparison of Mg–Yb and Mg–Ca Complexes

Abstract. Despite considerable progress in understanding the fundamental aspects of metal–metal bonding, lanthanide-metal bonding is limited to interaction

pubs.acs.org
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η6-Benzene Tetra-Anion Complexes of Early and Late Rare-Earth Metals | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

η6‑Benzene Tetra-Anion Complexes of Early and Late Rare-Earth Metals

Abstract. A novel synthetic route to the triple-decker benzene tetra-anion complexes [(η5-C5iPr5)­M­(μ:η6:η6-C6H6)­M­(η5-C5iPr5)] is reported for a range o

pubs.acs.org
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Big chelating ligands can be hard to crystalize with f elements. @RotermundBrian figured it out though #fblockrocks #americium pubs.acs.org/doi/10.1021/acs…

Insights into the Complexation of Actinides by Diethylenetriaminepentaacetic Acid from Characteri...

Abstract. Diethylenetriaminepentaacetic acid (DTPA) is a frequently used chelator in the nuclear and medical industries, especially for the complexation of

pubs.acs.org
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Come read the story behind these gorgeous americium crystals, reporting the first actinide DTPA crystal structure! @TEAS_Actinides #actinides #crystallography doi.org/10.1021/acs.inorgche…
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Theres three things i definitely like in life. Curium, diamonds, and water. #fblockrocks pubs.acs.org/doi/10.1021/jac…

High-Pressure Effects on an Octa-Hydrated Curium Complex: An Experimental and Theoretical Investi...

Abstract. An octa-hydrated curium compound [Cm­(H2O)8]­(Hdtp)­(dtp)·H2O (Cm1, H2dtp = 2,3-di­(tetrazol-5-yl)­pyrazine) along with its lanthanide analogues

pubs.acs.org
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ICYMI, from Jochen Autschbach, Stefan Minasian and co. at @BerkeleyLab, @UCB_Chemistry and @UBChemistry 'Synthesis and characterization of isostructural annulated actinocenes' pubs.rsc.org/en/content/arti…

Synthesis and characterization of isostructural annulated actinocenes†

An isostructural series of four annulated actinocene complexes, M(hdcCOT)2 (M = Th, U, Np, Pu), is reported. The syntheses proceed through a trivalent star

pubs.rsc.org
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Synthesis and Characterization of Homo- and Heteroleptic Neptunium(IV) Heteroarylalkenolate Complexes | Inorganic Chemistry pubs.acs.org/doi/10.1021/acs… Mathur, Gericke, and co-workers @InorgChem #neptunium #heteroarylalkenolate #ASAP_APCI_MS
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