We unravel how dirhodium catalysts build chiral sulfur centers, revealing an unexpected mechanistic blueprint through kinetics, spectroscopy, and computation. Congratulations, @MaheshHarariya and @Narmatha57 on your new paper! pubs.acs.org/inocaj/article/…

Congratulations to Mahesh @MaheshHarariya on successfully defending his PhD thesis! We sincerely thank Prof. R. B. Sunoj @sunojchemlab for graciously conducting the in-person thesis viva at @iiscbangalore, & Prof. Dean Tantillo @TantilloLab for his thorough review of the thesis.

Out now in @InorgChem! We reveal a previously unexplored triplet-state pathway in dirhodium tetracarboxylates facilitating phosphine ligand isomerization & orthometalation under mild conditions. Congrats @MaheshHarariya @Narmatha57 and @BibhasBorah doi.org/10.1021/acs.inorgche…

Congratulations to Ritwika @chatt_ritwika on successfully defending her PhD thesis! We sincerely thank Prof. Ankan Paul for graciously conducting the viva voce examination, and Prof. Dean Tantillo @TantilloLab for his thorough and meticulous review of the thesis.

New study out now in @JCIM_JCTC : QM/MM reveals the origin of stereodivergence in CALB-catalyzed transacylation tuned by noncovalent interactions. Congrats @MaheshHarariya and @balhara_reena! pubs.acs.org/doi/10.1021/acs…

Study from the group now out in @J_A_C_S: Engineered myoglobin reduces ketones via stepwise MHAT + PCET, clarifying elusive Fe–H intermediates. Axial ligands/electric fields tune reactivity—guiding new metalloenzyme design. Congrats @chatt_ritwika! pubs.acs.org/doi/10.1021/jac…

Our paper challenging the mechanism of Cu-catalyzed carbene insertion into N-H, O-H, & S-H bonds is published in JACS Au! 🎉 Congrats to co-first authors @arushiaol & @kritigu17669152! Thanks to @serbonline for funding! Read it here: pubs.acs.org/doi/full/10.102…